Hey sweet! I see they got you covered on calibration. If you hold it under a bright light the gradient inside will appear much brighter, and the eye piece should rotate to dial focus in to match your eye.
As for the IR gun, if you zap something cold 1st, like a concrete floor, then zap a leaf that is supposed to give you a much more accurate reading.
I remotely take air temp and RH, then quickly unzio the tent and zap a few leaves. Atmosphere changes quickly once the door is opened and leaves react fast.
Try to zap the ones under the hotspots of your light as they will be the extreme ones. I also zap the perimeter colas to help with propping them under better light. Remember the 10 hour rule for adjustments. Same for brix readings, so at the 10 hour mark after lights on, you can do both effectively.
Do you have a controller that tells VPD or will you be using a VPD calculator?
If you have a controller you need to enter the differential between air and leaf temp, so lets pretend air is 78F and leaf is 75F, you would enter a value of 3 in the controller app's "leaf temp offset" section, and if you are using either an online VPD calculator or a VPD calculator app, you want one with 3 input variables. Air temp, leaf temp, and RH.
The 2 input ones are weather VPD calculators and use a different formula.
Both the calculators and the controllers that have 3 inputs can do both plant and atmosphere VPD's simply by entering the leaf temp as the same as air temp, or by setting leaf temp offset to zero. The programming automatically flips from one formula to the other, so they are dual purpose.
Plant VPD is your rate of transpiration, and air VPD, the 2 input one for weather, is a reflection of the atmosphere's ability to absorb moisture.
When leaf temps are equal to or warmer than atmosphere, the plant is transpiring moisture out faster than atmosphere can wick it away, and stomata start to choke so they close, and CO2 intake is restricted. Everything gets stressed at that point.
A 3 input formula automatically compensates in the air's ability to wick, but the 2 input one won't compensate for leaf transpiration.
If you are comparing things to a chart, make sure it's a plant VPD chart and not an air VPD chart.