Great test, man.
Now I have a 64k question to everybody? What is PH and why does it change over time?
I believe your answer is here.
Understanding pH management and plant nutrition
Part 3: Fertilizers
Bill Argo, Ph.D.
Blackmore Company,
Solution pH and the effect that fertilizer has on substrate-pH two different aspects of water-soluble fertilizers
There is a great deal of confusion when it comes to understanding the difference between the pH of the fertilizer solution and the effect that fertilizer has on substrate pH, and why they are important to the health of your plants.
Just like with water pH, the pH of the fertilizer solution is a direct measurement of the balance between acidic hydrogen ions (H+) and basic hydroxide ions (OH-), and can be measured with a pH meter. The pH of a solution can range between 0 (very acidic) and 14 (very basic). At a pH of 7.0, the concentrations of H+ and OH- are equal, and the solution is said to be neutral. When the pH is above 7.0, the concentration of OH- is higher than H+, and the solution is said to be basic or alkaline (not to be confused with alkalinity). When the solution is below 7.0, the concentration of H+ is higher than OH-, and the solution is said to be acidic.
The effect that a water-soluble fertilizer has on substrate pH is dependent on the reactions that take place once the fertilizer has been applied to the crop and are based on the type of nitrogen contained in the fertilizer. There are three types of nitrogen used in water-soluble fertilizers: ammoniacal nitrogen (NH4-N), nitrate nitrogen (NO3-N) and urea (Figure 1).
Uptake of ammoniacal nitrogen causes the substrate-pH to decrease because H+ (acidic protons) are secreted from roots in order to balance the charges of ions inside the plant with the solution surrounding the outside of the roots. Urea is easily converted into ammoniacal nitrogen in the substrate and therefore can be thought of
as another source of ammoniacal nitrogen. In contrast, uptake of nitrate nitrogen increases substrate-pH
because OH-or HCO3- (bases) are secreted by plant roots in order to balance nitrate uptake.
Another important fertilizer reaction is a process called nitrification. Several types of bacteria in container substrates (including inert substrates like coir, bark, peat, rockwool, and scoria) convert ammoniacal nitrogen to nitrate nitrogen. Nitrification releases H+ (acidic protons), causing the substrate-pH to decrease.
Consider the difference in the amount of acidity supplied by a solution with a pH of 5.0 verses the amount of acidity supplied by 100 ppm of ammoniacal nitrogen.
A solution with a pH of 5.0 would supply about 0.01 mEq/liter of acidic hydrogen ions to the substrate. If all the 100 ppm ammoniacal nitrogen were converted into nitrate nitrogen through nitrification, the maximum amount of acidity produced would be 14.2 mEq/liter of acidic hydrogen, or about 1,400 times more acidity than would be supplied by a solution with a pH of 5.0. Put another way, applying 100 ppm of ammoniacal nitrogen has the potential to supply the same amount of acidity as a solution with a pH of 1.8. The acidity produced by a solution with a pH of 5.0 would be equivalent to the nitrification of 0.14 ppm ammoniacal nitrogen (almost undetectable).
While the effect that different nitrogen forms have on the substrate pH is more complicated than this simple example, it does give you an idea why
the nitrogen form of the fertilizer has a much greater effect on the substrate-pH than does the solution pH.
The main problem with predicting how the nitrogen form affects substrate pH is that the key reactions are not consistent. For example, the application nitrate nitrogen (NO3-N) can cause the substrate-pH to increase, but only if it is taken up by the plant. If plants are small, or are stressed and not growing, nitrate has little influence on substrate-pH.
The application of ammoniacal nitrogen (NH4-N) can cause the substrate-pH to decrease even if the plant is
small or is not growing, because in addition to plant uptake, nitrification will occur independently of the plant. However, nitrification is inhibited by low substrate-pH (starting at around 5.5), low substrate temperature (less than 60oF or 15o
C), and lack of oxygen through water-logging.
Finally, you never apply either all nitrate nitrogen or all ammoniacal nitrogen to your plants. Most fertilizer is a mixture of salts containing different forms of nitrogen and so the overall reaction produced by the fertilizer will depend on the ratio of the different nitrogen forms. There are also other factors that either magnify or buffer the reaction of the fertilizer including the substrate (cation exchange capacity, residual lime, decomposition – to be covered in a later article) and the irrigation water.