Below is info readily available at the Promix website for anyone to view.
What Changes Growing Medium pH?
Contrary to popular belief, the pH of the water does not influence the pH of the growing medium. Actually, it is the bicarbonate and carbonate levels in the water, known collectively as alkalinity, the potential acidity or basicity of the fertilizer and the plant itself:
Water Alkalinity
As stated above, water alkalinity is a measurement of carbonates and/or bicarbonates in the water, or another way to put it, is the amount of limestone dissolved in the irrigation water. The higher the alkalinity, the faster the pH of the growing medium climbs regardless of the water pH . If water is passed through a reverse osmosis unit, then alkalinity is very low, so the water does not cause the pH of the growing to rise quickly. Reverse osmosis units are not necessary for most water sources if the fertilizer is properly matched to the water profile and the crop grown.
Fertilizer
Quality water soluble fertilizers typically have the potential acidity or potential basicity posted on their labels to predict their influence on the pH of soilless growing medium. For example, the higher the potential acidity of the fertilizer, the more acid it is. This is often determined by the ratio of nitrogen forms. Ammonium and urea are acidic forms of nitrogen which cause growing medium pH to drop and nitrate is basic which causes growing medium pH to rise. Therefore, if your water has high alkalinity, a fertilizer that has a higher ratio of ammonium to nitrate can be used to minimize pH climb in a growing medium. Also, as a rule, most calcium-based fertilizers are alkaline and cause the pH of the growing medium to increase even if the water goes through a reverse osmosis unit.
Crop
When plants take up fertilizer elements through their roots, these elements all have either a negative charge or positive charge. The plant has to maintain its internal electrical balance, so in order to obtain a positively charged element, such as ammonium, potassium, calcium, magnesium, etc. the plant will release hydrogen into the growing medium, which causes a slight drop in pH near the plant root. Likewise, when a plant root takes up a negatively charged element such as nitrate, phosphorus, sulfate and most micronutrients, it will release hydroxide ions, which will cause a slight pH rise. Depending on the plant’s requirement for these individual elements, some use a higher ratio of positively charged fertilizer elements, so they are more efficient at acidifying the growing medium. Other plants use a higher ratio of negatively charged fertilizer elements, thus are more efficient at increasing the pH of the growing medium.
To review, the pH of the water does not influence or predict the pH of any growing medium. Adjusting the water pH to the ideal growing medium pH of 5.6-6.2 does not mean the pH of a growing medium will remain in this range. Often growers experience nutritional problems because the pH changes independently of the pH of the irrigation water.
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It may help in clearing some things up.
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