My suggestion was from the plants, but you asked about testing the leftover mix you have. I'd say do both.Alright, I have distilled water and have been wondering wouldn't it be a more accurate test if the medium used was from the actual plants?
See this:How many grams of medium mixed with how many milliliters of distilled water? Am I looking for mud? Peanut butter consistency? Milkshake? Nasty brown water?
Take samples from a few different places (dig down a bit rather than just use the top) and add an equivalent amount of distilled water as grams of soil (10 grams of soil, add 10ml water). If that doesn't make a slurry, use enough to make a stirrable thick slurry.
Stir it up, wait 15 minutes, stir again. Do that for at least an hour (longer is better), and then put your calibrated pH stick in the water. That's the pH of your medium.
You'll know how well you did if the pH of the unused mix you have around 5.8.Hey I did my due diligence and feel I have a pretty darn good ProMix knock off.