Just an FYI, runoff pH is not a thing (unless you're doing the complicated "pour through" test). A slurry test (with distilled water) is the way to see what the pH of your peat mix is.
In case you've never done one:
Take samples from a few different places (dig down a bit rather than just use the top) and add an equivalent amount of distilled water as grams of soil (10 grams of soil, add 10ml water). If that doesn't make a slurry, use enough to make a stirrable thick slurry.
Stir it up, wait 15 minutes, stir again. Do that for at least an hour (longer is better), and then put your calibrated pH stick in the water. That's the pH of your medium.