Hey Landracey,
I’m definitely not the best person to explain this… but mostly by studying the work of Miss Emilya Green and others here at 420 mag. When you water the ph drifts as it moves thru the column of soil in a container. When you adjust ph to 6.5 you are missing the lower end of the soil range which is 6.3
When nutes are out of range for the grow media used - those out if range nutes are invisible to the plant. Remember ph is a logarithmic scale so missing by a little still misses by a mile. Target ph for hydro, coco, hempy $ soilless is 5.8 but for soil 6.3
Assuming chelated (most bottle nutes) here’s how to mix your soup. Draw the water into your bucket. Add cal-mag first then stir & wait 10 minutes or as we call it ‘“smoke break”. Add your NPK stir & wait 10 mins. Adjust your ph to 6.3 and feed right away.
If possible it’s best to mix small fresh batches of nutes each time. Once you get a good handle on it with several successful harvests under your belt then you can experiment more. I know Bill284 mixes a few days worth at a time but bear in mind Mr Bill284l been doing this since before Jed Clampett struck oil. The point is premixed nutes from a few days ago can drift ph plus they can also bloom nasties depending on which nutes you select,
Emilya wrote a few books about ph via the FAQ pages here helping newbies like me to better understand. If you want to read more of her work go to 420 search bar up top and type in PH then put Emily Green in the user name box and hit enter. She’s not been active here for a year or two but her volume of work lives on.