I don't see why fresh air would need to come in if you're enriching with CO2, unless it's for human entry. If that is the case, personally if it it were me, I'd DIY a manifold to the intake of the A/C and put a duct near the ceiling so that it can pull air in from the outside. That way as the A/C cycles it is pulling in fresh air as well. You can put a sliding damper on the inlet for the duct outside the GR that blocks airflow back out when the AC is off, but opens up as as needed to allow the A/C to pull air in when you want to enter.
Now, on the inside, I would put a "Wye" split in the duct that also draws from a can filter to help control odor, as sealed rooms are never really sealed, and odor seeps out eventually with the changing of the seasons. This way when the damper is shut outside, the A/C can still breathe, but it is also acting as odor control as well. Just be sure to attach a can filter that is rated above the CFM of your A/C fan.
Now, on the inside, I would put a "Wye" split in the duct that also draws from a can filter to help control odor, as sealed rooms are never really sealed, and odor seeps out eventually with the changing of the seasons. This way when the damper is shut outside, the A/C can still breathe, but it is also acting as odor control as well. Just be sure to attach a can filter that is rated above the CFM of your A/C fan.