When I said "night length" I was referring to the dark period aka scotoperiod. Sure, at dawn and dusk there is a very brief period where the sunlight isn't bright enough, or dim enough, to affect the flowering hormones. In terms of photosynthesis, sure... the sun must get high enough in the sky to kick in. And sure, solar angle also affects this, throughout the day.
At any rate, both SF and Florida have longs nights at this time of year, more than 12 hours. So for outdoor plants, flowering would initiate in the middle of August (SF) and beginning of August (central FL). That's for a dark period of 10.5 hours. It would be later for sativas requiring 12 hours.