My advice is of course a little different.
I am forever going to ph my bites. Two big runs where the ph went off because the "buffer" Essentially broke down. Causing my plants to have soil issues, are use pro mix as well. She'd can explain the science of it better than I can But for me I just feel it lessens the weight on the buffer so it doesn't have so much fluctuation. If you will.
So far this round I am PH prior to feeding and I have no issues. So for me in my experience with pro mix and using mega crap nutrients I break the buffer sometimes. So I go to pH always.
Have you done a slurry test?
For breaks of stems and branches I use tape. It just pops open as it heals and grows. I too would take that green support you have us it does look like it's breaking through the stem. I would also go and get some sugar cane poles and use those as your support for your branches you just use the twist ties to secure them.
The science behind it is Here. It has to do with Nitrogen types (Amonical Nitrogen drives pH down, Nitrate Nitrogen drives it up). I too use Mega Crop with Pro-Mix, or my copy of Pro-Mix dubbed Faux-Mix®. Mega Crop is almost entirely Nitrate Nitrogen, so a long grow, with higher alkalinity water, can cause upward drift. @InTheShed had that issue. From Pro-Mix themselves, the solution is not to pH your nutes, but feed a fertilizer like Jacks 10-10-10 for several feeds. Why? It has a higher amount of Amonical Nitrogen in it and it will reduce the soil/substrate pH. You can't possibly run enough pH'd water through the container to "rebalance" the substrate. It would be the equivalent of trying to get drunk on non-alcoholic beer or high on hemp. The type of Nitrogen is far more powerful.