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Diatomaceous earth will do the little buggers in as well, on a side note ants will farm aphids, aphids bad.
Check for aphids. The ants may be farming aphids on your plants for their sugar. Aphids look a bit like scales on the stems and leaves.
Ants nest close to food, or their farms. If you kill the queen, you kill the colony.
Ants also cultivate fungi. Do you have mushrooms growing in your pots? Fungi under ground will look like very fine threads, like loose cotton balls.